|
|
2-Methyl-3-oxopropanoate + CoA + NAD+ + H2O <=> propionyl-CoA + HCO3- + NADH + H+
|
1.2.1.27
methylmalonate-semialdehyde dehydrogenase (CoA-acylating)
|
–
|
BM
|
|
BRENDA:
BR36776
MetaCyc:
1.2.1.27-RXN
|
|
|
|
3-hydroxy-2-methylpropanoate + NAD+ <=> 2-Methyl-3-oxopropanoate + NADH + H+
|
1.1.1.31
3-hydroxyisobutyrate dehydrogenase
1.1.1.59
3-hydroxypropionate dehydrogenase
|
–
–
|
B
|
|
BRENDA:
BR29294
KEGG:
R02047
SABIO-RK:
2065
|
|
|
|
(R)-3-Amino-2-methylpropanoate + pyruvate <=> 2-Methyl-3-oxopropanoate + L-alanine
|
2.6.1.40
(R)-3-amino-2-methylpropionate---pyruvate transaminase
|
–
|
BK
|
|
BRENDA:
BR47992
KEGG:
R02050
|
|
|
|
2-Methyl-3-oxopropanoate + CoA + NAD+ <=> propionyl-CoA + CO2 + NADH
|
1.2.1.18
malonate-semialdehyde dehydrogenase (acetylating)
1.2.1.27
methylmalonate-semialdehyde dehydrogenase (CoA-acylating)
|
–
–
|
K
|
|
BRENDA:
BS189112
KEGG:
R00922
SABIO-RK:
1242
|
|
|
|
4-hydroxy-2-keto-5-methyl-6-oxo-3-hexenoate + H2O <=> 2-Methyl-3-oxopropanoate + pyruvate
|
3.7.1
|
–
|
M
|
|
MetaCyc:
RXN-8824
|
|
|
|
3-aminoisobutanoate + propionaldehyde <=> 2-Methyl-3-oxopropanoate + Propylamine
|
2.6.1.18
beta-alanine---pyruvate transaminase
|
–
|
|
|
BRENDA:
BS437514
|
|
|
|
(R)-3-Amino-2-methylpropanoate + 2-oxobutyrate <=> 2-Methyl-3-oxopropanoate + 2-aminobutanoate
|
2.6.1.40
(R)-3-amino-2-methylpropionate---pyruvate transaminase
|
–
|
|
|
BRENDA:
BS359152
|
|
|
|
3-aminoisobutanoate + 2-oxoglutarate <=> 2-Methyl-3-oxopropanoate + L-glutamate
|
2.6.1.19
4-aminobutyrate---2-oxoglutarate transaminase
2.6.1.2
alanine transaminase
2.6.1.55
taurine---2-oxoglutarate transaminase
|
–
–
–
|
|
|
BRENDA:
BS353589
|
|
|
|
(S)-3-amino-2-methylpropanoate + 2-oxoglutarate <=> 2-Methyl-3-oxopropanoate + L-glutamate
|
2.6.1.22
(S)-3-amino-2-methylpropionate transaminase
|
–
|
|
|
BRENDA:
BR47416
|
|
|
|
(R)-3-hydroxyisobutyrate + NAD+ <=> 2-Methyl-3-oxopropanoate + NADH + H+
|
1.1.1.31
3-hydroxyisobutyrate dehydrogenase
1.1.1.59
3-hydroxypropionate dehydrogenase
|
–
–
|
|
|
BRENDA:
BS436657
|
|
|
|
L-3-hydroxyisobutyrate + NAD+ <=> 2-Methyl-3-oxopropanoate + NADH
|
1.1.1.31
3-hydroxyisobutyrate dehydrogenase
1.1.1.59
3-hydroxypropionate dehydrogenase
|
–
–
|
|
|
BRENDA:
BS373527
|
|
|
|
L-3-hydroxyisobutyrate + NADP+ <=> 2-Methyl-3-oxopropanoate + NADPH
|
1.1.1.276
serine 3-dehydrogenase (NADP+)
|
–
|
|
|
BRENDA:
BS355786
|
|
|
|
(S)-beta-hydroxyisobutyrate + NADP+ <=> 2-Methyl-3-oxopropanoate + NADPH + H+
|
1.1.1.31
3-hydroxyisobutyrate dehydrogenase
|
–
|
|
|
BRENDA:
BS451034
|
|
|
|
3-hydroxy-2-methylpropanoate + NADP+ <=> 2-Methyl-3-oxopropanoate + NADPH + H+
|
1.1.1.31
3-hydroxyisobutyrate dehydrogenase
|
–
|
|
|
BRENDA:
BS413201
|
|
|
|
(R)-3-Amino-2-methylpropanoate + 2-Oxopentanoate <=> 2-Methyl-3-oxopropanoate + L-norvaline
|
2.6.1.40
(R)-3-amino-2-methylpropionate---pyruvate transaminase
|
–
|
|
|
BRENDA:
BS359151
|
|
|
|
(R)-3-Amino-2-methylpropanoate + oxaloacetate <=> 2-Methyl-3-oxopropanoate + L-aspartate
|
2.6.1.40
(R)-3-amino-2-methylpropionate---pyruvate transaminase
|
–
|
|
|
BRENDA:
BS359149
|
|
|
|
(R)-3-Amino-2-methylpropanoate + glyoxylate <=> 2-Methyl-3-oxopropanoate + glycine
|
2.6.1.40
(R)-3-amino-2-methylpropionate---pyruvate transaminase
|
–
|
|
|
BRENDA:
BS359150
|
|
|
|
pyruvate + 3-aminoisobutanoate <=> L-alanine + 2-Methyl-3-oxopropanoate
|
2.6.1.18
beta-alanine---pyruvate transaminase
|
–
|
|
|
BRENDA:
BS353490
|
|
|
|
2-Methyl-3-oxopropanoate + NAD+ + H2O <=> propionate + H+ + CO2 + NADH
|
1.2.1.27
methylmalonate-semialdehyde dehydrogenase (CoA-acylating)
|
–
|
|
|
SABIO-RK:
14972
|
|